Radioactive Decay
The exponential decay law describes how the quantity of a radioactive substance decreases over time. The decay constant λ determines the rate. Larger λ means faster decay.
N(t) = N₀ e^(−λt)
Half-Life
The half-life is the time required for half the atoms in a sample to decay. It is the most commonly quoted measure of decay speed and is unique to each isotope.
t½ = ln(2) / λ
Mean Lifetime
The mean lifetime is the average time an atom survives before decaying. It is always longer than the half-life by a factor of 1/ln(2) ≈ 1.443.
τ = 1 / λ
Activity
Activity measures the number of disintegrations per second. The SI unit is the becquerel (Bq), equal to one decay per second. Higher activity means a more intensely radioactive sample.
A = λ N
How It Works
Radioactive decay follows an exponential law: N(t) = N₀e^(−λt). The decay constant λ determines how quickly a material decays. Related quantities include the half-life (t½ = ln2/λ), mean lifetime (τ = 1/λ), and activity (A = λN). Each isotope has a unique half-life, from microseconds to billions of years.
Example Problem
Carbon-14 has a half-life of 5,730 years. If a sample originally contained 1,000 atoms, how many remain after 11,460 years?
- Number of half-lives: 11,460 / 5,730 = 2
- Remaining: 1,000 × (½)² = 1,000 × 0.25 = 250 atoms
When to Use Each Variable
- Solve for Remaining Quantity — when you know the initial quantity, decay constant, and elapsed time, e.g., determining how much of a medical isotope remains after shipping.
- Solve for Half-Life — when you know the decay constant and want to express the decay rate in the most commonly quoted form.
- Solve for Mean Lifetime — when you need the average survival time per atom, e.g., calculating expected detection rates in a particle physics experiment.
- Solve for Activity — when you know the decay constant and number of atoms, e.g., determining the disintegration rate of a radioactive source in becquerels.
Key Concepts
Radioactive decay is a random process governed by the exponential law N(t) = N₀e^(−λt). The decay constant λ is unique to each isotope and determines the half-life (t½ = ln2/λ) and mean lifetime (τ = 1/λ). Activity (A = λN) measures disintegrations per second in becquerels. After n half-lives, the fraction remaining is (½)ⁿ.
Applications
- Radiometric dating: determining the age of archaeological artifacts (carbon-14) and geological formations (uranium-lead, potassium-argon)
- Nuclear medicine: calculating dose decay rates for radiopharmaceuticals like technetium-99m used in diagnostic imaging
- Radiation safety: estimating how long radioactive waste must be stored before activity drops to safe levels
- Nuclear power: tracking fuel burnup and predicting fission product inventories in reactor cores
Common Mistakes
- Confusing half-life with mean lifetime — mean lifetime is always 1.443× longer than half-life; using them interchangeably gives wrong decay rates
- Applying the decay formula to a mixture of isotopes without separating them — each isotope has its own λ and must be decayed independently
- Assuming activity is constant — activity decreases exponentially along with the number of atoms; a freshly produced medical isotope is far more active than the same sample a few half-lives later
Frequently Asked Questions
What is a half-life?
A half-life is the time it takes for half the atoms in a radioactive sample to decay. After two half-lives, one-quarter of the original atoms remain; after three, one-eighth, and so on.
What is the difference between half-life and mean lifetime?
The mean lifetime τ is the average survival time of an atom. It is always longer than the half-life by a factor of 1/ln(2) ≈ 1.443. Both are determined by the decay constant λ.
How is radioactive decay used in dating?
By measuring the ratio of a radioactive isotope to its decay product, scientists can calculate how long ago the material formed. Carbon-14 dating works for organic materials up to ~50,000 years old; uranium-lead dating covers billions of years.
Reference: Lindeburg, Michael R. 1992. Engineer In Training Reference Manual. Professional Publication, Inc. 8th Edition.
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